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Carbonation of polymeric organolithium compounds: Effects of chain end structure by Roderic P. Quirk; Jian Yin is a Materials Science article available to read on EtoBox.
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## Abstract The carbonation of the adduct of poly(styryl)lithium with 1,1‐diphenylethylene with gaseous carbon dioxide in benzene proceeds in high yield (>99%) compared to the inefficient functionalizations for poly(styryl)lithium (66%), poly(isoprenyl)lithium (59%), and polybutadienyl)lithium (27%). The quantitative carboxylation of poly(isoprenyl)lithium and poly(butadienyl)lithium requires the presence of larger amounts of Lewis bases such as THF ([THF]/[Li] = 300) or TMEDA ([TMEDA]/[Li] = 46) compared to poly(styryl)lithium in which a ratio of [TMEDA]/[Li] = 12 is effective. © 1992 John Wiley & Sons, Inc.
Who reads Carbonation of polymeric organolithium compounds: Effects of chain end structure?
It is typically read by researchers, students, and practitioners in Materials Science.
- Author
- Roderic P. Quirk; Jian Yin
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0887-624X)
- Published
- 1992
- Language
- EN
- Field
- Materials Science (Physical Sciences)