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Synthesis of novel branched ethylene/cyclopentene copolymers with only cis-1,3-enchained cyclopentene units using α-diimine nickel(II) complexes in the presence of methylaluminoxane by Hao Zou; Fangming Zhu; Qing Wu is a Materials Science article available to read on EtoBox.
What is Synthesis of novel branched ethylene/cyclopentene copolymers with only cis-1,3-enchained cyclopentene units using α-diimine nickel(II) complexes in the presence of methylaluminoxane about?
## Abstract The copolymerization of ethylene with cyclopentene catalyzed by three α‐diimine nickel(II) complexes in the presence of methylaluminoxane (MAO) was investigated. High‐molecular‐weight branched ethylene/cyclopentene copolymers with only __cis__‐1,3‐enchained cyclopentene units, which has not been reported previously, were obtained. The catalytic activity, cyclopentene incorporation, copolymer molecular weight, and molecular‐weight distribution could be controlled over a wide range through the variation of the catalyst structure and polymerization conditions, including cyclopentene concentration in the feed and polymerization temperature. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 2186–2192, 2008
Who reads Synthesis of novel branched ethylene/cyclopentene copolymers with only cis-1,3-enchained cyclopentene units using α-diimine nickel(II) complexes in the presence of methylaluminoxane?
It is typically read by researchers, students, and practitioners in Materials Science.
- Author
- Hao Zou; Fangming Zhu; Qing Wu
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0887-624X)
- Published
- 2008
- Language
- EN
- Field
- Materials Science (Physical Sciences)