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Determination of inorganic arsenic species in natural waters—Benefits of separation and preconcentration on ion exchange and hybrid resins by Nureddin Ben Issa; Vladana N. Rajaković-Ognjanović; Branislava M. Jovanović; Ljubinka V. Rajaković is a scholarly article available to read on EtoBox.
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A simple method for the separation and determination of inorganic arsenic (iAs) species in natural and drinking water was developed. Procedures for sample preparation, separation of As(III) and As(V) species and preconcentration of the total iAs on fixed bed columns were defined. Two resins, a strong base anion exchange (SBAE) resin and a hybrid (HY) resin were utilized. The inductively-coupled plasma-mass spectrometry method was applied as the analytical method for the determination of the arsenic concentration in water. The governing factors for the ion exchange/sorption of arsenic on resins in a batch and a fixed bed flow system were analyzed and compared. Acidity of the water, which plays an important role in the control of the ionic or molecular forms of arsenic species, was beneficial for the separation; by adjusting the pH values to less than 8.00, the SBAE resin separated As(V) from As(III) in water by retaining As(V) and allowing As(III) to pass through. The sorption activity of the hydrated iron oxide particles integrated into the HY resin was beneficial for bonding of all iAs species over a wide range of pH values from 5.00 to 11.00. The resin capacities were calculated
- Author
- Nureddin Ben Issa; Vladana N. Rajaković-Ognjanović; Branislava M. Jovanović; Ljubinka V. Rajaković
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0003-2670)
- Published
- 2010
- Language
- EN