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Synthesis of Novel Tri-podal Mesogenic Alkenes and Side-chain Polysiloxanes by Tomasz Ganicz; Włodzimierz A. Stańczyk is a Chemistry article available to read on EtoBox.

What is Synthesis of Novel Tri-podal Mesogenic Alkenes and Side-chain Polysiloxanes about?

Low molecular weight tri-podal biphenyl-and benzoate-type mesogens [C 6 H 5 C 6 H 4 O(CH 2 ) 5 SiMe 2 CH 2 CH 2 SiMe 2 ] 3 CH (4), [C 11 H 23 O(C 6 H 4 ) 2 O(CH 2 ) 5 SiMe 2 ] 3 CH (5) and [MeOC 6 H 4 OC(O)C 6 H 4 O(CH 2 ) 5 SiMe 2 ] 3 CH (6) (C 6 H 4 = 1,4-phenylene) were obtained, from branched silyl substituted methane precursors [CH 2 ‚CH(Me) 2 Si] 3 CH ( ) and (HMe 2 Si) 3 CH (2). The biphenyl-containing ones (4) and ( ) were converted into terminal alkenes, which were subsequently hydrosilylated with poly(methylsiloxanes). The polymer derived from (5) exhibited mesomorphic properties. Such systems have the potential to significantly increase the density of liquid crystal rod-like structures in side chains of linear polymers (or dendritic liquid crystal polymers).

Who reads Synthesis of Novel Tri-podal Mesogenic Alkenes and Side-chain Polysiloxanes?

It is typically read by researchers, students, and practitioners in Chemistry.

Author
Tomasz Ganicz; Włodzimierz A. Stańczyk
Publisher
Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)
Published
2004
Language
EN
Field
Chemistry (Physical Sciences)

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