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Can I read Some Cyclopropene Rearrangements on EtoBox?
Some Cyclopropene Rearrangements by R. Breslow; R. Boikess; M. Battiste is a Chemistry article available to read on EtoBox.
What is Some Cyclopropene Rearrangements about?
RECEWCIY Chandross and Smolins!q reported the rearrangement of triphenylcyclopropenyl azide to triphenyltriazine.1 As they noted in their paper, we had also observed th.Ts interestins reaction, and me wish to report here some other cases in which ring expansion: occur by internal attack of a substituent attached to the saturated carbon of a diphenylcyclopropene derivative. The most closely related example comes from the attempt to prepay the hydrazone of 1,~diphenyl-3-benxoylcyclopropene. Although an oxime of this compound is easily prepared, reaction of the ketone Wi%h hydrazine hydrate in refluxing ethanol led to 3,4,6-triphenyE dihydropyridazine, identified by comparison of this compound and its dehydrogenation product with autnentic samples.
Who reads Some Cyclopropene Rearrangements?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- R. Breslow; R. Boikess; M. Battiste
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)
- Published
- 1960
- Language
- EN
- Field
- Chemistry (Physical Sciences)