About this Chemistry article
Asymmetric Synthesis of β-Dialkylamino Alcohols by Transfer Hydrogenation of α-Dialkylamino Ketones by Tomasz Kosmalski; Andrzej Wojtczak; Marek Zaidlewicz is a Chemistry article available to read on EtoBox.
Transfer hydrogenation of representative aryl and heteroaryl dialkylaminomethyl ketones with formic acid-triethylamine, catalyzed by RuCl[(R,R)-TsDPEN](g-p-cymene), produces the corresponding b-dialkylamino alcohols, 97-99% ee, in 50-73% yields.
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- Author
- Tomasz Kosmalski; Andrzej Wojtczak; Marek Zaidlewicz
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0957-4166)
- Published
- 2009
- Language
- EN
- Field
- Chemistry (Physical Sciences)