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Can I read A New Method of Constructing Dearomatized Compounds Using Triazene on EtoBox?
A New Method of Constructing Dearomatized Compounds Using Triazene by Keiji Nishiwaki; Takashi Ogawa; Ken-ichi Tagami; Genzoh Tanabe; Osamu Muraoka; Keizo Matsuo is a Chemistry article available to read on EtoBox.
What is A New Method of Constructing Dearomatized Compounds Using Triazene about?
We are reporting on a new method of constructing dearomatized compounds from a-substituted aryltriazenes. Deprotonation occurs at C atom a to N3. Nucleophilic attack of generated anion at the ortho-position of aryl group forms a new carbon-carbon bond. A stereoselective reaction was observed when the substituents on the C a to N3 are tied together in either a pyrrolidine or a piperidine. The product of this reaction possessed an interesting dearomatized tetrahydrobenzotriazine framework.
Who reads A New Method of Constructing Dearomatized Compounds Using Triazene?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Keiji Nishiwaki; Takashi Ogawa; Ken-ichi Tagami; Genzoh Tanabe; Osamu Muraoka; Keizo Matsuo
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4020)
- Published
- 2006
- Language
- EN
- Field
- Chemistry (Physical Sciences)