About this Materials Science article
Construction of Two Mixed-ligand Coordination Polymers Presenting Unusual Polyrotaxane-like Entanglements by Yongnian Yan; Siyu Liu; Mingming Guo; Xianmin Guo; Huadong Guo is a Materials Science article available to read on EtoBox.
Two novel polyrotaxane-like coordination polymers, [Ni4(L)4(H2O)3(bpp)4]·3H2O (1) and [Cd4(L)4(bpp)3]·3H2O (2) (H2L=Me2Si(p-C6H4COOH)2, bpp=1,3-bis(4-pyridyl)propane), have been synthesized and structurally characterized. Compound 1 features a 2D→3D polyrotaxane array by the interlock of bilayer networks. Compound 2 exhibits an unusual 3D polyrotaxane-like self-threading framework. In addition, compound 2 shows an emission at 485nm when it was excitated at 400nm.
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- Author
- Yongnian Yan; Siyu Liu; Mingming Guo; Xianmin Guo; Huadong Guo
- Published
- 2016
- Language
- EN
- Field
- Materials Science (Physical Sciences)