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What is Diastereoselective Cycloaddition of Pyrylium Ylides about?
This paper discusses the diastereoselective 1,3-dipolar cycloaddition of pyrylium ylides with chiral enamides, resulting in cycloadducts with high yields and stereoselectivity. The study highlights the successful removal of chiral auxiliaries and the first asymmetric synthesis of complex amine 8. The findings suggest that amides can act as effective alkene activators in these cycloaddition reactions.
- Author
- Keven Barrette
- Language
- EN