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Anti-corrosion behavior of two N2O4 Schiff-base ligands: Experimental and theoretical studies 1 1 Introduction 1 2 Experimental and computational details 3 2.1 Preparation of electrodes 3 2.2 Test solution 3 2.3 Chemicals and synthesis of inhibitor 3 2.3.1 Synthesis of 2,2’-((1Z,1′Z)-(((1,2-phenylenebis(oxy))bis(2,1-phenylene)) bis (methanylylidene))bis(azanylylidene))die ... 3 2.3.2 Synthesis of 2,2’-((1Z,1′Z)-(((propane-1,3-diylbis(oxy))bis(2,1-phenylene)) bis (methanylylidene))bis(azanylylidene)) ... 3 2.4 Electrochemical measurements 4 2.5 Surface topography test 5 2.6 Density functional theory analysis 5 2.6.1 Monte Carlo and Molecular Dynamic simulation 5 3 Results and discussion 5 3.1 Electrochemical results 5 3.1.1 Polarization curves 5 3.1.2 Electrochemical impedance spectroscopy 5 3.2 DFT results 6 3.2.1 Monte Carlo and molecular dynamic simulations 8 3.3 Surface analysis 8 4 Conclusion 8 Author agreement statement 8 Declaration of competing interest 9 References 9

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nonfiction