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This document provides an overview of polyatomic molecular spectra. It begins by comparing the rotational spectra of diatomic and polyatomic molecules. Polyatomic molecules are classified based on the relative magnitudes of their principal moments of inertia. Examples of linear, symmetric top, and spherical top molecules are given. The rotational spectra of linear molecules can be treated similarly to diatomics, while symmetric tops have two quantum numbers due to two main rotation directions. Bond lengths

Author

pioneleon

Language

EN