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Synthesis of (±)-Zeapyranolactone, a Noncanonical Strigolactone Isolated from Maize, and Determination of Its Overall Relative Configuration by Chinatsu Ono-Ogasawara; Shunya Yamamoto; Yusuke Ogura; Hironori Okamura; Kiyofumi Takaba; Satoshi Yoshida; Sota Sato; Koji Yonekura; Hirosato Takikawa is a Chemistry article available to read on EtoBox.
What is Synthesis of (±)-Zeapyranolactone, a Noncanonical Strigolactone Isolated from Maize, and Determination of Its Overall Relative Configuration about?
Strigolactones are a class of apocarotenoids known as rhizosphere semiochemicals and plant hormones. They are classified as either canonical, with a tricyclic lactone (ABC ring) and a butenolide (D ring) comprising their basic skeleton, or noncanonical, deviating from the basic skeleton. Here, zeapyranolactone, a noncanonical strigolactone isolated from maize, was synthesized for the first time as a racemic and diastereomeric mixture, and its relative stereochemistry was determined by three-dimensional electron diffraction crystallography as 4S\*,4aS\*,2′R\*. The synthetic route developed is straightforward and does not rely on the use of typical protective groups.
Who reads Synthesis of (±)-Zeapyranolactone, a Noncanonical Strigolactone Isolated from Maize, and Determination of Its Overall Relative Configuration?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Chinatsu Ono-Ogasawara; Shunya Yamamoto; Yusuke Ogura; Hironori Okamura; Kiyofumi Takaba; Satoshi Yoshida; Sota Sato; Koji Yonekura; Hirosato Takikawa
- Publisher
- Elsevier BV
- Published
- 2023
- Language
- EN
- Field
- Chemistry (Physical Sciences)