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Enhanced Thermal Stability of Planar Perovskite Solar Cells Through Triphenylphosphine Interface Passivation by M. Thambidurai; Mohamed I. Omer; Foo Shini; Herlina Arianita Dewi; Nur Fadilah Jamaludin; Teck Ming Koh; Xiaohong Tang; Nripan Mathews; Cuong Dang is a Engineering article available to read on EtoBox.

What is Enhanced Thermal Stability of Planar Perovskite Solar Cells Through Triphenylphosphine Interface Passivation about?

## Abstract While extensive research has driven the rapid efficiency trajectory noted to date for organic–inorganic perovskite solar cells (PSCs), their thermal stability remains one of the key issues hindering their commercialization. Herein, a significant reduction in surface defects (a precursor to perovskite instability) could be attained by introducing triphenylphosphine (TPP), an effective Lewis base passivator, to the vulnerable perovskite/spiro‐OMeTAD interface. Not only did TPP passivation enable a high power conversion efficiency (PCE) of 20.22 % to be achieved, these devices also exhibited superior ambient and thermal stability. Unlike the pristine device, which exhibited a sharp descend to 16 % of its initial PCE on storing in relative humidity of 10 %, at 85 °C for more than 720 h, the TPP‐passivated devices retained 71 % of its initial PCE. Hence, this study presents a facile yet excellent approach to attain high‐performing yet thermally stable PSCs.

Who reads Enhanced Thermal Stability of Planar Perovskite Solar Cells Through Triphenylphosphine Interface Passivation?

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Author
M. Thambidurai; Mohamed I. Omer; Foo Shini; Herlina Arianita Dewi; Nur Fadilah Jamaludin; Teck Ming Koh; Xiaohong Tang; Nripan Mathews; Cuong Dang
Publisher
Wiley
Published
2022
Language
EN
Field
Engineering (Physical Sciences)

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