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The Dimer of Heptafulveneiron Tricarbonyl by Amihai Eisenstadt; J.Mitchell Guss; Ronald Mason is a Chemistry article available to read on EtoBox.
What is The Dimer of Heptafulveneiron Tricarbonyl about?
The preparation of the fluxional methyltropyliumiron tricarbonyl from two different precursors is described. Attempts to convert the salt into the parent complex of heptafulvene-Fe(C0)3 provides a dimer, C,,H,,Fe,O,, whose structure has been determined by extensive deuterium labelling and NMR spectroscopy, and by X-ray diffraction methods. The dimer is formed by addition across the exocyclic double bond, the electrocyclic dimerisation [which is the formally non-allowed (8 + 8) n-cycloaddition] being promoted by the metal tricarbonyl fragment. The intramolecular bonding in 3,3'-ethano-l,l'-bis(cyclohepta-2,4,6-trienyl)diiron hexacarbonyl is discussed together with its mechanism of formation.
Who reads The Dimer of Heptafulveneiron Tricarbonyl?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Amihai Eisenstadt; J.Mitchell Guss; Ronald Mason
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)
- Published
- 1974
- Language
- EN
- Field
- Chemistry (Physical Sciences)
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