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Statistical Thermodynamics of Long Straight Rigid Rods on Triangular Lattices: Nematic Order and Adsorption Thermodynamic Functions by Matoz-Fernandez, D. A.; Linares, D. H.; Ramirez-Pastor, A. J. is a scholarly article available to read on EtoBox.
What is Statistical Thermodynamics of Long Straight Rigid Rods on Triangular Lattices: Nematic Order and Adsorption Thermodynamic Functions about?
The statistical thermodynamics of straight rigid rods of length $k$ on triangular lattices was developed on a generalization in the spirit of the lattice-gas model and the classical Guggenheim-DiMarzio approximation. In this scheme, the Helmholtz free energy and its derivatives were written in terms of the order parameter $\delta$, which characterizes the nematic phase occurring in the system at intermediate densities. Then, using the principle of minimum free energy with $\delta$ as a parameter, the main adsorption properties were calculated. Comparisons with Monte Carlo simulations and experimental data were performed in order to evaluate the reaches and limitations of the theoretical model.
- Author
- Matoz-Fernandez, D. A.; Linares, D. H.; Ramirez-Pastor, A. J.
- Published
- 2012
- Language
- EN
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