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Can I read Influence of the Central Metal on the Crystal Structures and Electronic Structures of Biferrocene Trinuclear Complexes on EtoBox?
Influence of the Central Metal on the Crystal Structures and Electronic Structures of Biferrocene Trinuclear Complexes by Zhao-Di Liu; Xuan-Jun Zhang; Jie-Ying Wu; Fu-Ying Hao; Hong-Ping Zhou; Yu-Peng Tian is a Chemistry article available to read on EtoBox.
What is Influence of the Central Metal on the Crystal Structures and Electronic Structures of Biferrocene Trinuclear Complexes about?
Five metal-bridged biferrocene complexes of the Schiff-base ligand (HL = S-benzyl-N-(ferrocenyl-1methyl-methylidene)dithiocarbazate) have been studied by single crystal X-ray diffraction and 57 Fe Mössbauer spectroscopy. The crystal structures of the complexes show that the central metal ions are tetra-coordinated by two ligands in two modes: the central d 8 transition metal ions (Ni 2+ , Pd 2+ , and Pt 2+ ) are nearly square-planar coordinated and the d 10 transition metal ions (Zn 2+ and Cd 2+ ) are tetrahedrally coordinated. Interestingly, the isomer shifts in 57 Fe Mössbauer spectroscopy are also of two kinds: d 8 transition metal ions (0.097-0.247 mm/s) and d 10 transition metal ions (0.416-0.435 mm/s).
Who reads Influence of the Central Metal on the Crystal Structures and Electronic Structures of Biferrocene Trinuclear Complexes?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Zhao-Di Liu; Xuan-Jun Zhang; Jie-Ying Wu; Fu-Ying Hao; Hong-Ping Zhou; Yu-Peng Tian
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0277-5387)
- Published
- 2011
- Language
- EN
- Field
- Chemistry (Physical Sciences)