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Reactions of perfluoroaromatic compounds with ethereal solutions of methylmagnesium iodide in the presence of silver(I) and copper(I) salts by A.A. Bogachev; L.S. Kobrina; G.G. Yakobson is a Chemistry article available to read on EtoBox.

What is Reactions of perfluoroaromatic compounds with ethereal solutions of methylmagnesium iodide in the presence of silver(I) and copper(I) salts about?

The reactions of hexafluorobenzene, octafluorotoluene, decafluorodiphenyl, and octafluoronaphthalene with ethereal eolutions of methylmagnesium iodide in the presence of AgCl or CuI gave the products of the methylation and l-ethoxyethylation of the perfluorinated eubstratee, whose formation hae been suggested to occur with participation of free radicale. Substitution of fluorine atoms by the l-ethoxyethyl radicals in C F CF and C6F5C6F5 proceeds with predominant 65 3 para-orientation; in C,0F8, I-and 2-orientations take place to 831 equal extent, whereas the methyl radicals attack mainly the l-position of octafluoronaphthalene and show a low eelectivity in the reaction with octafluorotoluene. \* Yields calculated from the GLC data; \*\* Considering the ieolated products.

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Author

A.A. Bogachev; L.S. Kobrina; G.G. Yakobson

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-1139)

Published

1990

Language

EN

Field

Chemistry (Physical Sciences)