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Can I read Automerization on [4.2.2]Propella-2,4,7,9-tetraene System on EtoBox?

Automerization on [4.2.2]Propella-2,4,7,9-tetraene System by Takashi Tsuji; Shinya Nishida is a Chemistry article available to read on EtoBox.

What is Automerization on [4.2.2]Propella-2,4,7,9-tetraene System about?

7-[4.2.2]Propella-2,4,7,9\_tetraenecarboxylates, A, when heated at 200°, undergo reversible automerization giving 2 in preference to the aromatization to naphthalene derivatives which is promoted by free radicals. In a recent communication, 1 we have reported the synthesis of methyl 7-[4.2.2]propella-2,4,7,9\_tetraenecarboxylate, &. During the subsequent investigation on the chemical behavior of I&,, we observed that h underwent a novel automerization when heated at 200' in solution. Valence isomerization of unsaturated polycyclic compounds has been a subject of much attention and studied

Who reads Automerization on [4.2.2]Propella-2,4,7,9-tetraene System?

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Author
Takashi Tsuji; Shinya Nishida
Publisher
Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)
Published
1983
Language
EN
Field
Chemistry (Physical Sciences)

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