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The document discusses the first Suzuki–Miyaura type cross-coupling of ortho-azidobromobenzene with arylboronic acids, leading to the synthesis of fused aromatic indole-heterocycles. This method involves Pd-catalyzed reactions and thermally induced nitrene insertion, demonstrating its effectiveness in producing biologically relevant compounds. Additionally, it highlights the preparation of 4-amino-a-carboline as a versatile intermediate through similar cross-coupling techniques.

Author

Adelina Sonia

Language

EN