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Raman spectra of gases: 24—Phenol by H. William Wilson; R. W. Macnamee; J. R. Durig is a Chemistry article available to read on EtoBox.

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## Abstract The medium resolution Raman spectrum of gaseous phenol has been recorded between 4000 and 50 cm^−1^ using the 5145 Å line of an argon laser. A number of __a__′ bands have been observed which correspond to previously assigned normal modes, but lines at 1388 and 1285 cm^−1^, which are not normally observed in the infrared spectrum of the gas, have been assigned as fundamentals. In addition, a strong Raman band at 1007 cm^−1^ is probably an overtone of an out‐of‐plane vibration at 503 cm^−1^ in resonance with a nearby __a__′ fundamental. Two bands at 824 and 810 cm^−1^ were both found to belong to the symmetric __a__′ species. Previous assignments have dealt with these two bands as having different symmetries. A reassignment of some of the fundamentals of phenol may be necessary to account for these Raman observations.

Who reads Raman spectra of gases: 24—Phenol?

Author

H. William Wilson; R. W. Macnamee; J. R. Durig

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0377-0486)

Published

1981

Language

EN

Field

Chemistry (Physical Sciences)