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End-grafting Copolymers of Styrene and 4-Vinylpyridine on an Interacting Solid Surface by Zhijun Chen; Jie Cai; Leyang Zhang; Yun Liu; Xiqun Jiang; Changzheng Yang is a Materials Science article available to read on EtoBox.

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## Abstract Copolymers of styrene and 4‐vinylpyridine with a styrene fraction __f__ varying from 1 to 0 were grafted onto a silicon substrate in the melt. The grafting reaction and the stability of the grafted chains were investigated by Fourier transform infrared and X‐ray photoelectron spectroscopy. The thickness and surface morphology of the grafted copolymer layers were characterized with ellipsometry and atomic force microscopy (AFM). The copolymer chains were successfully grafted to the surface of the silicon substrate by a reaction between the hydroxyl groups of the nitroxide moiety at the end of the copolymers and the silanol groups on the surface of the silicon wafer. A measurement of the thickness of the grafted copolymer layers showed that the ratio of grafted‐layer thickness to the unperturbed chain radius of gyration decreased with the increasing fraction of 4‐vinylpyridine in the copolymer; this indicated that the grafted layer was strongly attracted to the substrate. In addition, an accelerated grafting process was observed at grafting times ranging from 48 to 72 h for pure poly(4‐vinylpyridine) and copolymers with __f__ values of 0.3 and 0.5. AFM observation reveale

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Author

Zhijun Chen; Jie Cai; Leyang Zhang; Yun Liu; Xiqun Jiang; Changzheng Yang

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0887-6266)

Published

2005

Language

EN

Field

Materials Science (Physical Sciences)