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Can I read Metal-directed assembly of large dinuclear copper(II) dithiocarbamate macrocyclic complexes on EtoBox?
Metal-directed assembly of large dinuclear copper(II) dithiocarbamate macrocyclic complexes by James Cookson; Emma A.L. Evans; John P. Maher; Christopher J. Serpell; Rowena L. Paul; Andrew R. Cowley; Michael G.B. Drew; Paul D. Beer is a Chemistry article available to read on EtoBox.
What is Metal-directed assembly of large dinuclear copper(II) dithiocarbamate macrocyclic complexes about?
The synthesis of a range of dinuclear Cu(II) dithiocarbamate (dtc)-based macrocycles and their characterisation are described. By carefully tuning the size of the aromatic spacer, cavities of different dimensions can be designed. The length and flexibility of the chosen spacer group dictates the intermetallic distance and hence the degree of communication between the two metal centres as evidenced by electrochemical and EPR experiments. This is illustrated by crystallographic evidence that show the macrocycles can host guests (such as CH 2 Cl 2 ) or can fold and form unexpected Cu(I) dtc clusters.
Who reads Metal-directed assembly of large dinuclear copper(II) dithiocarbamate macrocyclic complexes?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- James Cookson; Emma A.L. Evans; John P. Maher; Christopher J. Serpell; Rowena L. Paul; Andrew R. Cowley; Michael G.B. Drew; Paul D. Beer
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0020-1693)
- Published
- 2010
- Language
- EN
- Field
- Chemistry (Physical Sciences)