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Effective utilization of waste ash from MSW and coal co-combustion power plant—Zeolite synthesis by Yun Fan; Fu-Shen Zhang; Jianxin Zhu; Zhengang Liu is a Environmental Science article available to read on EtoBox.

The solid by-product from power plant fueled with municipal solid waste and coal was used as a raw material to synthesize zeolite by fusionhydrothermal process in order to effectively use this type of waste material. The effects of treatment conditions, including NaOH/ash ratio, operating temperature and hydrothermal reaction time, were investigated, and the product was applied to simulated wastewater treatment. The optimal conditions for zeolite X synthesis were: NaOH/ash ratio = 1.2:1, fusion temperature = 550 • C, crystallization time = 6-10 h and crystallization temperature = 90 • C. In the synthesis process, it was found that zeolite X tended to transform into zeolite HS when NaOH/ash ratio was 1.8 or higher, crystallization time was 14-18 h, operating temperature was 130 • C or higher. The CEC value, BET surface area and pore volume for the synthesized product at optimal conditions were 250 cmol kg -1 , 249 m 2 g -1 and 0.46 cm 3 g -1 respectively, higher than coal fly ash based zeolite. Furthermore, when applied to Zn 2+ contaminated wastewater treatment, the synthesized product presented larger adsorption capacity and bond energy than coal fly ash based zeolite, and the ads

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Author
Yun Fan; Fu-Shen Zhang; Jianxin Zhu; Zhengang Liu
Publisher
Elsevier Science; Elsevier ; Elsevier BV (ISSN 0304-3894)
Published
2008
Language
EN
Field
Environmental Science (Physical Sciences)