Can I read Syntheses and Structural Characterization of Heterometallic Bis(pyrazolyl)methane Complexes of Rhenium and Platinum on EtoBox?

Syntheses and Structural Characterization of Heterometallic Bis(pyrazolyl)methane Complexes of Rhenium and Platinum by Daniel L. Reger; Russell P. Watson; Mark D. Smith is a Chemistry article available to read on EtoBox.

What is Syntheses and Structural Characterization of Heterometallic Bis(pyrazolyl)methane Complexes of Rhenium and Platinum about?

The new heterometallic complex {l-1,3,5-[CH(pz) 2 ] 3 C 6 H 3 }[Re(CO) 3 Br][Pt(p-tolyl) 2 ] 2 has been prepared by reaction of 1 equiv. of the dimer [Pt(p-tolyl) 2 (l-SEt 2 )] 2 with the monometallic rhenium precursor {1,3,5-[CH(pz) 2 ] 3 C 6 H 3 }Re(CO) 3 Br, where 1,3,5-[CH(pz) 2 ] 3 C 6 H 3 is the tritopic, arene-linked bis(pyrazolyl)methane ligand 1,3,5-tris[bis(1-pyrazolyl)methyl]benzene. Similarly, the heterometallic complex {l-1,3,5-[CH(pz) 2 ] 3 C 6 H 3 }[Re(CO) 3 Br] 2 [Pt(p-tolyl) 2 ] has been made by the reaction of the dirhenium compound {l-1,3,5-[CH(pz) 2 ] 3 -C 6 H 3 }[Re(CO) 3 Br] 2 and one-half of an equivalent of [Pt(p-tolyl) 2 (l-SEt 2 )] 2 . X-ray crystallographic studies of the new compounds reveal significant noncovalent interactions in their molecular and supramolecular structures.

Who reads Syntheses and Structural Characterization of Heterometallic Bis(pyrazolyl)methane Complexes of Rhenium and Platinum?

Author

Daniel L. Reger; Russell P. Watson; Mark D. Smith

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)

Published

2007

Language

EN

Field

Chemistry (Physical Sciences)