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Can I read A ^13^C NMR Study of the Products and Mechanism of the Thermal Oxidative Degradation of Poly(ethylene oxide) on EtoBox?
A ^13^C NMR Study of the Products and Mechanism of the Thermal Oxidative Degradation of Poly(ethylene oxide) by Omar A. Mkhatresh; Frank Heatley is a Materials Science article available to read on EtoBox.
What is A ^13^C NMR Study of the Products and Mechanism of the Thermal Oxidative Degradation of Poly(ethylene oxide) about?
## Abstract The products and mechanism of the thermal oxidative degradation of poly(ethylene oxide) at 150 °C have been analysed using ^13^C NMR spectroscopy. The analysis was assisted by the use of distortionless enhancement by polarisation transfer spectra, longitudinal relaxation time measurements, long‐range ^13^C^1^H coupling and chemical shift simulation software. The major result of degradation was chain scission resulting in two formate ester chain ends. Minor products were in‐chain esters, peroxy groups, oxymethylene links and hydroxy and methoxy chain ends. Initial steps for the mechanism of chain scission. magnified imageInitial steps for the mechanism of chain scission.
Who reads A ^13^C NMR Study of the Products and Mechanism of the Thermal Oxidative Degradation of Poly(ethylene oxide)?
It is typically read by researchers, students, and practitioners in Materials Science.
- Author
- Omar A. Mkhatresh; Frank Heatley
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley (ISSN 1022-1352)
- Published
- 2002
- Language
- EN
- Field
- Materials Science (Physical Sciences)