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Can I read Photoinduced Radical Sulfinylation of C(sp^3^)–H Bonds with Sulfinyl Sulfones on EtoBox?
Photoinduced Radical Sulfinylation of C(sp^3^)–H Bonds with Sulfinyl Sulfones by Heping Tan; Changmei Zhang; Yangling Deng; Mengxuan Zhang; Xiya Cheng; Jie Wu; Danqing Zheng is a Chemistry article available to read on EtoBox.
What is Photoinduced Radical Sulfinylation of C(sp^3^)–H Bonds with Sulfinyl Sulfones about?
A direct C(sp 3 )−H sulfinylation reaction of alkanes with sulfinyl sulfones via decatungstate photocatalysis is reported. The sulfinyl sulfones generated in situ from sulfinates in the presence of an acylating reagent were able to trap the alkyl radicals that were produced via the photoinduced direct hydrogen atom transfer of alkanes, leading to a range of sulfoxides. This radical sulfinylation process provides an efficient and concise method for the synthesis of sulfoxides from abundant alkanes under mild conditions. Using the same strategy, aldehydes can also be transferred to the corresponding sulfoxides via decarbonylative sulfinylation.
Who reads Photoinduced Radical Sulfinylation of C(sp^3^)–H Bonds with Sulfinyl Sulfones?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Heping Tan; Changmei Zhang; Yangling Deng; Mengxuan Zhang; Xiya Cheng; Jie Wu; Danqing Zheng
- Publisher
- American Chemical Society (ACS)
- Published
- 2023
- Language
- EN
- Field
- Chemistry (Physical Sciences)