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Solution Thermodynamics and Its Application to Aqueous Solutions : A Differential Approach by Yoshikata Koga is a nonfiction available to read on EtoBox.

What is Solution Thermodynamics and Its Application to Aqueous Solutions : A Differential Approach about?

As the title suggests, we introduce a novel differential approach to solution thermodynamics and use it for the study of aqueous solutions. We evaluate the quantities of higher order derivative than the normal thermodynamic functions. We allow these higher derivative data speak for themselves without resorting to any model system. We thus elucidate the molecular processes in solution, (referred to in this book "mixing scheme"), to the depth equal to, if not deeper, than that gained by spectroscopic and other methods. We show that there are three composition regions in aqueous solutions of non-electrolytes, each of which has a qualitatively distinct mixing scheme. The boundary between the adjacent regions is associated with an anomaly in the third derivatives of G. The loci of the anomalies in the temperature-composition field form the line sometimes referred as "Koga line". We then take advantage of the anomaly of a third derivative quantity of 1-propanol in the ternary aqueous solution, 1-propanol - sample species - H2O. We use its induced change as a probe of the effect of a sample species on H2O. In this way, we clarified what a hydrophobe, or a hydrophile, and i

Who reads Solution Thermodynamics and Its Application to Aqueous Solutions : A Differential Approach?

Author

Yoshikata Koga

Publisher

Elsevier Science & Technology Books

Published

2007

Language

EN

ISBN

9780444530738

Category

nonfiction

Subjects

Technology, Science, Chemistry