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Can I read Inhibition of the electrooxidation of Cr(II) by adsorbed Cr(NCS)3 on EtoBox?
Inhibition of the electrooxidation of Cr(II) by adsorbed Cr(NCS)3 by Dale Hall; A.L. Feliu; D.A. Aikens is a Chemistry article available to read on EtoBox.
What is Inhibition of the electrooxidation of Cr(II) by adsorbed Cr(NCS)3 about?
The electrooxidation of Cr(II) in the presence of 1--10 mM thiocyanate is inhibited over a wide potential range by adsorbed Cr(NCS)3. Blocking of the electrode and a repulsive diffuse double layer effect appear to be the major inhibiting mechanisms. The inhibition is removed at anodic potentials probably by faradaic removal of Cr(NCS)3 and at cathodic potentials by reduction of Cr(NCS) 3. Under the latter conditions an anodic "pseudo-prewave" is observed. The electroreduction of Cr(III)-thiocyanate complexes is discussed as it relates to the controlled potential electrooxidation of Cr(II) in the presence of thiocyanate and as it influences the electrooxidation of Cr(II).
Who reads Inhibition of the electrooxidation of Cr(II) by adsorbed Cr(NCS)3?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Dale Hall; A.L. Feliu; D.A. Aikens
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-0728)
- Published
- 1977
- Language
- EN
- Field
- Chemistry (Physical Sciences)