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Hydrogen Bonding and Tautomerism in Anils of Salicylaldehydes and Related Compounds. A Study of Deuterium Isotope Effects on 13C Chemical Shifts by Alan R. Katritzky; Ion Ghiviriga; Peter Leeming; Ferenc Soti is a Chemistry article available to read on EtoBox.

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Deuterium-induced chemical shift differences on the 13C (DIS) are reported for a series of Schiff bases of salicylaldehydes, l-(phenyliminomethyl)naphthalen-2-ol and 4-chloro-1,7-phenanthrolin-l0-ol. Provided that corrections for the hydrogen donor atom and diamagnetic effects of the surrounding groups are made, plots of logarithms of two bond DIS vs. the chemical shift of the exchangeable proton are linear for compounds in which tautomeric equilibria are absent or strongly displaced in favor of one form. Molecules with comparably populated tautomers in fast exchange fall off this correlation. By this method, anils of salicylaldehydes were found to exist as hydroxy forms with localized hydrogen bonds while l-(phenyliminomethyl)naphthalen-2-ol and 4-chloro-1,7-phenanthrolin-10-01 were found to be tautomeric mixtures dominated by the hydroxy forms. DIS also revealed that 4-chlor-1,7phenanthrolin-10-01 exists in solution as an aggregate of two molecules.

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Author

Alan R. Katritzky; Ion Ghiviriga; Peter Leeming; Ferenc Soti

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; John Wiley and Sons Ltd; Wiley (ISSN 0749-1581)

Published

1996

Language

EN

Field

Chemistry (Physical Sciences)