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The Protonation of CF~3~SO~3~H: Preparation and Characterization of Trifluoromethyldihydroxyoxosulfonium Hexafluoridoantimonate, CF~3~SO~3~H~2~^+^SbF~6~^–^ by Theresa Soltner; Nadine R. Goetz; Andreas Kornath is a Chemistry article available to read on EtoBox.

What is The Protonation of CF~3~SO~3~H: Preparation and Characterization of Trifluoromethyldihydroxyoxosulfonium Hexafluoridoantimonate, CF~3~SO~3~H~2~^+^SbF~6~^–^ about?

Trifluoromethanesulfonic anhydride reacts with superacidic solutions AF/SbF 5 (A = H, D) to form their corresponding salts CF 3 SO 3 A 2 + SbF 6 -, which are protonated forms of trifluoromethanesulfonic acid and CF 3 SO 2 F as by-product. The salts have been characterized by vibrational spectroscopy and single-crystal structural analysis. CF 3 SO 3 H 2 + SbF 6 -crystallizes in the triclinic space group P1 ̄with two formula units

Who reads The Protonation of CF~3~SO~3~H: Preparation and Characterization of Trifluoromethyldihydroxyoxosulfonium Hexafluoridoantimonate, CF~3~SO~3~H~2~^+^SbF~6~^–^?

Author

Theresa Soltner; Nadine R. Goetz; Andreas Kornath

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley (ISSN 1434-1948)

Published

2011

Language

EN

Field

Chemistry (Physical Sciences)