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Synthesis and magnetism of copper(II)-lanthanide(III) heterometal binuclear complexes with N,N′-bis(2-aminoethyl)oxamidocopper(II) by Yan-tuan Li; Zong-hui Jiang; Shu-lin Ma; Xiao-ying Li; Dai-zheng Liao; Shi-ping Yan; Geng-Lin Wang is a Chemistry article available to read on EtoBox.
What is Synthesis and magnetism of copper(II)-lanthanide(III) heterometal binuclear complexes with N,N′-bis(2-aminoethyl)oxamidocopper(II) about?
novel p-oxamido heterometal binuclear complexes have been synthesized and characterized, namely Cu(oxae)Ln(L)2(C104)3, where oxae denotes the N,N'-bis(2aminoethyl) oxamido dianion, L denotes 1, lo-phenanthroline (abbreviated as phen) and Ln represents Eu, Gd, Tb, Dy, Ho or Er. The magnetic susceptibility of Cu(oxae)Gd(phen), (C104)3 was measured over the range 4-300 K and the observed data were successfully simulated by an equation based on the spin Hamiltonian operator (fi = -2J$ -$), giving the exchange integral J(Cu-Gd) = -0.62 cn-'. This indicates a weak antiferromagnetic interaction between the copper(I1) and godolinium(II1) ions.
Who reads Synthesis and magnetism of copper(II)-lanthanide(III) heterometal binuclear complexes with N,N′-bis(2-aminoethyl)oxamidocopper(II)?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Yan-tuan Li; Zong-hui Jiang; Shu-lin Ma; Xiao-ying Li; Dai-zheng Liao; Shi-ping Yan; Geng-Lin Wang
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0277-5387)
- Published
- 1994
- Language
- EN
- Field
- Chemistry (Physical Sciences)