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ESR spectra of the square pyramidal iodo [difluoro[3,3′-(trimethylenedinitrilo)-bis(2-butanone oximato)] borato] copper(II) complex by A. Bencini; D. Gatteschi; C. Zanchini; M. Wicholas is a Chemistry article available to read on EtoBox.

What is ESR spectra of the square pyramidal iodo [difluoro[3,3′-(trimethylenedinitrilo)-bis(2-butanone oximato)] borato] copper(II) complex about?

## The single crystal ESR spectrum of the square pyramidal iodo[difluoro[3,3?(trimethylenedinitrilo)bis(2-butanoneoximato)] borate] copper(H), cu-(cyclops)I, complex diluted into the nickel(U) lattice has been recorded. of cyclops, we decided to record the single crystal ESR spectrum of Cu(cyclops)I doped into the nickel analog, and wish to report here these results together with an Angular Overlap analysis of the spectrum. i%e spin Hamiltonian parameters (gl = 2.05, g2 = 2.07, g3 = 2.18, A3 = 190 X IK4 cm-') have been interpreted using a symmetry independent angular overlap model. This analysis shows that the in-plane field is fairly strong thus explaining the observed diamagnetism of the Ni(cyclops)X adducts. ## Experimental Cu(cyclops)C104 has been prepared as previously described [ 1 ] . A similar procedure has been followed for obtaining the nickel complex.

Who reads ESR spectra of the square pyramidal iodo [difluoro[3,3′-(trimethylenedinitrilo)-bis(2-butanone oximato)] borato] copper(II) complex?

Author

A. Bencini; D. Gatteschi; C. Zanchini; M. Wicholas

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0020-1693)

Published

1981

Language

EN

Field

Chemistry (Physical Sciences)