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(Bu4N)[Re{NB(C6F5)3}Cl4(OH2)] – Struktur und EPR-Spektren by U. Abram; F. J. Kohl; K. Öfele; W. A. Herrmann; A. Voigt; R. Kirmse is a Chemistry article available to read on EtoBox.

What is (Bu4N)[Re{NB(C6F5)3}Cl4(OH2)] – Struktur und EPR-Spektren about?

The title compound represents the first structurally characterized rhenium(VI) complex with a bridging nitrido ligand. It has been prepared by the reaction of (Bu 4 N)[ReNCl 4 ] with B(C 6 F 5 ) 3 in CH 2 Cl 2 . An almost linear (170.5(3)°) nitrido bridge with a Re≡N bond length of 1.672(4) A Ê is formed. The coordination position trans to the multiple bond is occupied by a molecule of water. The EPR parameters of the title complex are reported and discussed with those of [ReNCl 4 ] ± concerning the spin-density distribution in the ``ReNCl 4 o unit.

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Author

U. Abram; F. J. Kohl; K. Öfele; W. A. Herrmann; A. Voigt; R. Kirmse

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); Wiley - V C H Verlag GmbbH & Co.; Wiley (ISSN 0372-7874)

Published

1998

Language

DE

Field

Chemistry (Physical Sciences)