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Can I read Rhodium-Catalyzed C═N Bond Formation through a Rebound Hydrolysis Mechanism and Application in β-Lactam Synthesis on EtoBox?
Rhodium-Catalyzed C═N Bond Formation through a Rebound Hydrolysis Mechanism and Application in β-Lactam Synthesis by Long Chen; Linxing Zhang; Ying Shao; Guangyang Xu; Xinhao Zhang; Shengbiao Tang; Jiangtao Sun is a Chemistry article available to read on EtoBox.
What is Rhodium-Catalyzed C═N Bond Formation through a Rebound Hydrolysis Mechanism and Application in β-Lactam Synthesis about?
A rhodium-catalyzed reaction of N-hydroxyanilines with diazo compounds to produce α-imino esters was developed. Distinct from the commonly accepted 1,2-H transfer for normal X-H insertion reactions, density functional theory calculations indicate that this transformation proceeds via a novel rebound hydrolysis mechanism. Furthermore, a three-component reaction was explored to synthesize highly functionalized β-lactams in good yields and diastereoselectivities.
Who reads Rhodium-Catalyzed C═N Bond Formation through a Rebound Hydrolysis Mechanism and Application in β-Lactam Synthesis?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Long Chen; Linxing Zhang; Ying Shao; Guangyang Xu; Xinhao Zhang; Shengbiao Tang; Jiangtao Sun
- Publisher
- American Chemical Society (ACS)
- Published
- 2019
- Language
- EN
- Field
- Chemistry (Physical Sciences)