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Homogeneous chromium(VI)-catalyzed oxidations of allylic alcohols by alkyl hydroperoxides: Influence of the nature of the alkyl group on the product distribution by Abdelkhalek Riahi; Françoise Hénin; Jacques Muzart is a Chemistry article available to read on EtoBox.

What is Homogeneous chromium(VI)-catalyzed oxidations of allylic alcohols by alkyl hydroperoxides: Influence of the nature of the alkyl group on the product distribution about?

The chromium oxide-catalyzed oxidation of allylic alcohols -RIcH(OH)CR2=CItR 3 -by ROOH (R= t-Bu, PhCMe2) affords generally a mixture of RIcocR2=CItR 3 and RIcH=CR2COR 3. The rate of the reaction and the ratio between the two oxidized compounds both depend on the nature of R. It has been concluded that the oxidative species and the reactive intermediates c(mtain this R group.

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Author

Abdelkhalek Riahi; Françoise Hénin; Jacques Muzart

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)

Published

1999

Language

EN

Field

Chemistry (Physical Sciences)