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Can I read Critical Triple Roles of Sodium Iodide in Tailoring the Solventized Structure, Anode-electrolyte Interface and Crystal Plane Growth to Achieve Highly Reversible Zinc Anodes for Aqueous Zinc-ion Batteries on EtoBox?
Critical Triple Roles of Sodium Iodide in Tailoring the Solventized Structure, Anode-electrolyte Interface and Crystal Plane Growth to Achieve Highly Reversible Zinc Anodes for Aqueous Zinc-ion Batteries by Xiaomin Huang; Qingping Li; XiaoQin Zhang; Heng Cao; Jingxin Zhao; Yu Liu; Qiaoji Zheng; Yu Huo; Fengyu Xie; Bingang Xu; Dunmin Lin is a Chemistry article available to read on EtoBox.
What is Critical Triple Roles of Sodium Iodide in Tailoring the Solventized Structure, Anode-electrolyte Interface and Crystal Plane Growth to Achieve Highly Reversible Zinc Anodes for Aqueous Zinc-ion Batteries about?
Aqueous rechargeable Zn-ion batteries (ARZIBs) are promising for energy storage. However, the Zn dendrite and corrosive reactions on the surface of Zn anode limit the practical uses of ARZIBs. Herein, we present a valid electrolyte additive of NaI, in which I- can modulate the morphology of Zn crystal growth by adsorbing on specific crystal surfaces (002), and guide Zn deposition by inducing a negative charge on the Zn anode. Simultaneously, it enhances the reduction stability of water molecules by participating in the solvation structure of Zn(H2O)6 2+ by forming ZnI(H2O)5 +. At 10 mA cm−2, the assembled Zn symmetrical batteries can run stably over 1,100 h, and the depth of discharge (DOD) can reach 51.3 %. At 1 A g−1, the VO2||Zn full-cell in 2 M ZnCl2 electrolyte with 0.4 M NaI (2 M ZnCl2-0.4 M NaI) maintains of the capacity retention of 75.7 % over 300 cycles. This work offers an insight into inorganic anions as electrolyte additives for achieving stable zinc anodes of ARZIBs.
Who reads Critical Triple Roles of Sodium Iodide in Tailoring the Solventized Structure, Anode-electrolyte Interface and Crystal Plane Growth to Achieve Highly Reversible Zinc Anodes for Aqueous Zinc-ion Batteries?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Xiaomin Huang; Qingping Li; XiaoQin Zhang; Heng Cao; Jingxin Zhao; Yu Liu; Qiaoji Zheng; Yu Huo; Fengyu Xie; Bingang Xu; Dunmin Lin
- Publisher
- Elsevier BV
- Published
- 2023
- Language
- EN
- Field
- Chemistry (Physical Sciences)