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Can I read Substitution Effects in Intramolecular Aziridine–allylsilane Cyclizations on EtoBox?
Substitution Effects in Intramolecular Aziridine–allylsilane Cyclizations by David J. Lapinsky; Aravinda B. Pulipaka; Stephen C. Bergmeier is a Chemistry article available to read on EtoBox.
What is Substitution Effects in Intramolecular Aziridine–allylsilane Cyclizations about?
We report here the synthesis of an aziridine tethered to a substituted allylsilane via a substituted tether. These tether-substituted aziridine-allylsilanes cyclize differently upon treatment with BF 3 $OEt 2 than tether-unsubstituted aziridine-allylsilanes and provide a 6-endo-type product. We show that steric interactions between the N-substituent of the aziridine and substitution on the tether can control the product distribution.
Who reads Substitution Effects in Intramolecular Aziridine–allylsilane Cyclizations?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- David J. Lapinsky; Aravinda B. Pulipaka; Stephen C. Bergmeier
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4020)
- Published
- 2009
- Language
- EN
- Field
- Chemistry (Physical Sciences)
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