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On the stereochemistry of allylmetal-aldehyde condensations. Preliminary communication by Scott E. Denmark; Eric J. Weber is a Chemistry article available to read on EtoBox.
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## Abstract The stereochemical course of the intramolecular allylsilane‐aldehyde condensation of **1a** has been investigated. A modest preference for the product arising from a synclinal orientation of double bonds was observed with __Lewis__‐acid catalysts. Cyclization induced by fluoride ion resulted in stereochemical reversal.
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- Author
- Scott E. Denmark; Eric J. Weber
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); Wiley-Blackwell; Wiley (ISSN 0018-019X)
- Published
- 1983
- Language
- DE
- ISBN
- 9781983066061
- Field
- Chemistry (Physical Sciences)