Can I read The Utilization of Solid State Chemistry Reaction Routes as New Syntheses Strategies for the Coordination Chemistry of Rare Earth Amides on EtoBox?
The Utilization of Solid State Chemistry Reaction Routes as New Syntheses Strategies for the Coordination Chemistry of Rare Earth Amides by Klaus Müller-Buschbaum is a Chemistry article available to read on EtoBox.
What is The Utilization of Solid State Chemistry Reaction Routes as New Syntheses Strategies for the Coordination Chemistry of Rare Earth Amides about?
## Abstract Solvent free high‐temperature reactions in melts are well known procedures in Solid‐State Chemistry. Although the reaction conditions are extreme considering the properties of organic ligands they can also be utilized for Coordination Chemistry and offer a fruitful alternative to usual solvent treatments. This includes the chemistry of organic amides of the rare earth elements. The avoidance of any solvent renders novel homoleptic complexes accessible but also implies difficulties bound to the solid state of the reaction mixtures. The high chemical affinity of the rare earth elements towards halides and especially oxygen limits known homoleptic amides obtained via solvent treatments mostly to multi‐chelating ligands like porphyrines, calix‐pyrroles etc. With no special conditions met like a high steric demand, solvent molecules as co‐coordinating partners enforce the formation of heteroleptic species. This influence can be avoided by the use of completely solvent free reactions, such as melt reactions in which a solid is reacted directly with a melt or with a substance under solvothermal conditions. The high reactivity of the rare earth metals allows the direct oxidatio
Who reads The Utilization of Solid State Chemistry Reaction Routes as New Syntheses Strategies for the Coordination Chemistry of Rare Earth Amides?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Klaus Müller-Buschbaum
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); Wiley - V C H Verlag GmbbH & Co.; Wiley (ISSN 0372-7874)
- Published
- 2005
- Language
- DE
- Field
- Chemistry (Physical Sciences)