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Oxidative Crosslinking Polymerization of Poly[(methyl Methacrylate)-co-(2-(n-pyrrolyl)ethyl Methacrylate)] with Iron Chloride in Nitromethane by Dietmar Stanke; Manfred L. Hallensleben; Levent Toppare is a Materials Science article available to read on EtoBox.

What is Oxidative Crosslinking Polymerization of Poly[(methyl Methacrylate)-co-(2-(n-pyrrolyl)ethyl Methacrylate)] with Iron Chloride in Nitromethane about?

Poly[(methyl methacrylate)-co-(2-(N-pyrrolyl)ethyl methacrylate)] (PMMA-co-PEMA, 1) containing 0,7 to 7 mol-% pyrrolylethyl methacrylate (PEMA) units was crosslinked via oxidative polymerization with FeCl, in inert atmosphere. The properties of the products 2 depended on the amount of electroactive side groups and on the molecular weight of the precursor copolymers 1 as well as on the reaction conditions. Crosslinking between pendant pyrrolegroups and an increase in the glass transition temperature in the oxidative coupling could be avoided using precursor copolymers 1 with low PEMA content (< 1 mol-Yo).

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Author

Dietmar Stanke; Manfred L. Hallensleben; Levent Toppare

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley (ISSN 1022-1352)

Published

1995

Language

CY

Field

Materials Science (Physical Sciences)