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Structure and thermal decomposition of μ-1,1-azido bridged dinuclear Fe(III) complexes by Filiz Ercan; B. Meltem Ates; Levent Aksu; Hüseyin Sözeri; Ismail Ercan; Orhan Atakol is a Materials Science article available to read on EtoBox.
What is Structure and thermal decomposition of μ-1,1-azido bridged dinuclear Fe(III) complexes about?
Fe(III) complexes were prepared by the reaction of two different ONNO type Schiff bases N,N′-bis (salicylidene)-1,3-propanediamine (LH~2~) and N,N′-bis (salicylidene)-2,2′-dimethyl-1,3-propane diamine (LDMH~2~) in N^−^ ~3~ containing medium. The X-ray diffraction studies revealed that the complexes are of dinuclear type connected with __μ__-1,1-azido bridges. It was observed from the thermogravimetric analyses of the complexes that the azide group decomposed around 200 °C with exothermic reaction. This exothermic decomposition did not affect the rest of the molecule. Following the decomposition of the azide group the remainder of the molecule decomposed with carbonization process. It was seen that the molecule decomposed into Fe~2~O~3~ above 650 °C in oxygen containing medium. [FeLDMN~3~]~2~ complex was found to have N~4~O~2~ distorted octahedral sphere with Fe...Fe distance of 3.414 Å.
Who reads Structure and thermal decomposition of μ-1,1-azido bridged dinuclear Fe(III) complexes?
It is typically read by researchers, students, and practitioners in Materials Science.
- Author
- Filiz Ercan; B. Meltem Ates; Levent Aksu; Hüseyin Sözeri; Ismail Ercan; Orhan Atakol
- Publisher
- Walter de Gruyter GmbH
- Published
- 2007
- Language
- EN
- Field
- Materials Science (Physical Sciences)