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What is Racemization in Camphene Rearrangement about?

1. The document describes a new route to optically active camphenilone using C14-labeled methyl iodide. 2. Camphenilone is converted to methylcamphenilol and then to optically active camphene labeled at the 8-position via a xanthate dehydration. 3. Racemization of camphene via standard rearrangement procedures and analysis shows the C14 is statistically distributed among the 8-, 9-, and 10-positions, indicating racemization occurs partly by migration of a gem-methyl group and partly by an alternative pro

Author

Akshay Kaushik

Language

EN