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An Open-Framework Germanate with Polycubane-Like Topology by Hailian Li; Mohamed Eddaoudi; Omar M. Yaghi is a Chemistry article available to read on EtoBox.

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Body-centered Ge parallelepiped building blocks form the basis of the structure of [Ge O (OH) ]⋅2 (H ppz)⋅0.5 (H O) (ASU-14, ppz=piperazine). In this new structure type for an open-framework germanate (see picture for a section of the structure) the building blocks are linked together at each of their eight vertices to give the rare polycubane topology with an intersecting channel system of ten- and eight-membered rings (pore sizes 5×6 and 4×4 Å , respectively) in which the piperazinium cations and water molecules reside.

Who reads An Open-Framework Germanate with Polycubane-Like Topology?

Author

Hailian Li; Mohamed Eddaoudi; Omar M. Yaghi

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley; Research Square (ISSN 0044-8249)

Published

1999

Language

EN

Field

Chemistry (Physical Sciences)