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Insertion reactions of diethylaluminium derivatives VI. Reactions of bis(diethylaluminium) sulfide and diethylaluminium thiolate or amide with esters by T Hirabayashi; H Imaeda; K Itoh; Y Ishii is a Chemistry article available to read on EtoBox.

What is Insertion reactions of diethylaluminium derivatives VI. Reactions of bis(diethylaluminium) sulfide and diethylaluminium thiolate or amide with esters about?

The reactions of bis(diethylaluminium) sulfide with organic esters gave stable l/l adducts. Elimination of diethylaluminium alcoholate was observed when large alkyl substituents were present in the esters. Similar elimination of diethylaluminium alcoholate occurred in the reactions of diethylaluminium thiolate or amide, Et,AlX (X=SEt or NMe,), with esters to give the corresponding thioesters or amides.

Who reads Insertion reactions of diethylaluminium derivatives VI. Reactions of bis(diethylaluminium) sulfide and diethylaluminium thiolate or amide with esters?

Author

T Hirabayashi; H Imaeda; K Itoh; Y Ishii

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)

Published

1972

Language

EN

Field

Chemistry (Physical Sciences)