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Can I read Electrochemical fluorination of aliphatic aldehydes and cyclic ketones using Et3N-5HF electrolyte on EtoBox?
Electrochemical fluorination of aliphatic aldehydes and cyclic ketones using Et3N-5HF electrolyte by Sheng-Qi Chen; Tsuyoshi Hatakeyama; Tsuyoshi Fukuhara; Shoji Hara; Norihiko Yoneda is a Engineering article available to read on EtoBox.
What is Electrochemical fluorination of aliphatic aldehydes and cyclic ketones using Et3N-5HF electrolyte about?
The first electrochemical oxidative fluorination of aliphatic aldehydes (1) and cyclic ketones (3) has been successfully carried out using Base-HF as the supporting electrolyte and fluorine source. The selective displacement of formyl hydrogen by fluorine in aliphatic aldehydes electrochemically took place to give acyl fluorides (2) in good yields in the presence of the Et3N-5HF electrolyte. On the other hand, the selective a-bond cleavage between the carbonyl carbon and substituted a-carbon in cyclic ketones occurred in the presence of the EtjN-5HF electrolyte to give fluoroacyl fluorides (4), which were readily converted in good yields to the corresponding fluorocarboxylic esters (5) by the subsequent alcoholysis.
Who reads Electrochemical fluorination of aliphatic aldehydes and cyclic ketones using Et3N-5HF electrolyte?
It is typically read by researchers, students, and practitioners in Engineering.
- Author
- Sheng-Qi Chen; Tsuyoshi Hatakeyama; Tsuyoshi Fukuhara; Shoji Hara; Norihiko Yoneda
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0013-4686)
- Published
- 1997
- Language
- EN
- Field
- Engineering (Physical Sciences)