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Magnetostructural correlations in heteroleptic nickel(II) complexes by J. Titiš; R. Boča; L’. Dlháň; T. Ďurčeková; H. Fuess; R. Ivaniková; V. Mrázová; B. Papánková; I. Svoboda is a Chemistry article available to read on EtoBox.
What is Magnetostructural correlations in heteroleptic nickel(II) complexes about?
Heteroleptic nickel(II) complexes with the general formula Ni(L) m (H 2 O) n (X) k , have been synthesized and structurally characterized; L stands for neutral N-donor ligands: 4-benzofuropyridine (bzfupy), dimethylfuropyridine (Me 2 fupy) and 1,2-dimethylimidazole (Me 2 iz), 2 N 2 }, {NiO 4 N 2 } and {NiN 4 O 2 } chromophores, respectively. These complexes and two other previously characterized complexes, [Ni(pz) 4 (ac) 2 ], pz -pyrazole, and [Ni(L NN ) 2 (H 2 O) 2 ], L NN -bidentate chelating ligand, were subjected to magnetochemical investigation down to 2 K (susceptibility and magnetization measurements). They show magnetic behaviour typical for zero-field splitting systems. The axial parameter of the zero-field splitting, D, adopts either positive or negative values and correlates with the axial distortion of the coordination polyhedra.
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- Author
- J. Titiš; R. Boča; L’. Dlháň; T. Ďurčeková; H. Fuess; R. Ivaniková; V. Mrázová; B. Papánková; I. Svoboda
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0277-5387)
- Published
- 2007
- Language
- EN
- Field
- Chemistry (Physical Sciences)