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ChemInform Abstract: MAO-Catalyzed Allylzirconation of 1-Alkynes. by S. YAMANOI; T. IMAI; T. MATSUMOTO; K. SUZUKI is a Chemistry article available to read on EtoBox.

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MAO-Catalyzed Allylzirconation of 1-Alkynes. -Hydrozirconation of the allene (I) followed by Et3Al catalyzed reaction with ethynylbenzene is found to result in selective formation of the heptadiene (III). However, using methoxyaluminoxane (MOA) as catalyst gives a remarkably enhanced regioselectivity for (III). Further application of the MOA-catalysis to various substrate combinations leads to similar results. -(YAMANOI, S.; IMAI, T.;

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Author

S. YAMANOI; T. IMAI; T. MATSUMOTO; K. SUZUKI

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); Wiley (ISSN 0931-7597)

Published

1997

Language

EN

Field

Chemistry (Physical Sciences)