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Bis(2-amino-1-benzylpyridinium) bis(2,2-dicyanoethene-1,1-dithiolato-κ2S,S′)nickelate(II) by Hou, Yong ;Huang, Qian ;Zuo, Hongrong ;Ni, Chunlin is a Chemistry article available to read on EtoBox.

What is Bis(2-amino-1-benzylpyridinium) bis(2,2-dicyanoethene-1,1-dithiolato-κ2S,S′)nickelate(II) about?

, was obtained by the direct reaction of NiCl 2 Á6H 2 O, K 2 imnt and (Bz2NH 2 py) + ÁBr À in water. The Ni II ion lies on an inversion centre and the asymmetric unit contains a (Bz2NH 2 py) + cation and one-half of the Ni(imnt) 2 2À anion. The Ni II ion adopts a square-planar coordination geometry. In the crystal structure, N-HÁ Á ÁN and C-HÁ Á ÁN hydrogen bonds are observed between the anions and the cations.

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Author

Hou, Yong ;Huang, Qian ;Zuo, Hongrong ;Ni, Chunlin

Publisher

International Union of Crystallography; Chester UK: International Union of Crystallography, 2001-2014.; [S.l.]: Wiley-Blackwell; [Chester]: 2008-; International Union of Crystallography (IUCr) (ISSN 1600-5368)

Published

2007

Language

EN

Field

Chemistry (Physical Sciences)