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Can I read Reactions of the cationic monobut-2-yne complex [WI(CO)(NCMe)(dppm)(η2-MeC2Me)][BF4] {dppm = Ph2P(CH2)PPh2} with carbon monoxide and tButylisonitrile on EtoBox?
Reactions of the cationic monobut-2-yne complex [WI(CO)(NCMe)(dppm)(η2-MeC2Me)][BF4] {dppm = Ph2P(CH2)PPh2} with carbon monoxide and tButylisonitrile by Paul K. Baker; Kevin R. Flower is a Chemistry article available to read on EtoBox.
What is Reactions of the cationic monobut-2-yne complex [WI(CO)(NCMe)(dppm)(η2-MeC2Me)][BF4] {dppm = Ph2P(CH2)PPh2} with carbon monoxide and tButylisonitrile about?
The compound [WI(CO)(NCMe)(dppm)(n'-Me&-Me)] [BF,] reacts with carbon monoxide and tbutylisonitrile in CH2Cla at room temperature to give the substituted products [WI(CO),(dppm)(n2-MeC2Me)]-[BF,] (I) and [WI(CO)(CNtBu)(dppm)(n2-MeC2Me)] [BF,] (2) in good yield. The new complexes were fully characterised by elemental analysis, infrared, 'H and 13C NMR spectroscopy. i3C NMR spectroscopy suggests that the but-2-yne ligand is donating four electrons to the tungsten in these complexes.
Who reads Reactions of the cationic monobut-2-yne complex [WI(CO)(NCMe)(dppm)(η2-MeC2Me)][BF4] {dppm = Ph2P(CH2)PPh2} with carbon monoxide and tButylisonitrile?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Paul K. Baker; Kevin R. Flower
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0020-1693)
- Published
- 1989
- Language
- EN
- Field
- Chemistry (Physical Sciences)