Can I read An Unexpected Photoelectronic Effect from [Co(en)~3~]~2~(Zr~2~F~12~)(SiF~6~)⋅4 H~2~O, a Compound Containing an H‐Bonded Assembly of Discrete [Co(en)~3~]^3+^, (Zr~2~F~12~)^4−^, and (SiF~6~)^2−^ Ions on EtoBox?

An Unexpected Photoelectronic Effect from [Co(en)~3~]~2~(Zr~2~F~12~)(SiF~6~)⋅4 H~2~O, a Compound Containing an H‐Bonded Assembly of Discrete [Co(en)~3~]^3+^, (Zr~2~F~12~)^4−^, and (SiF~6~)^2−^ Ions by Yu Du; Min Yang; Jihong Yu; Qinhe Pan; Ruren Xu is a Chemistry article available to read on EtoBox.

What is An Unexpected Photoelectronic Effect from [Co(en)~3~]~2~(Zr~2~F~12~)(SiF~6~)⋅4 H~2~O, a Compound Containing an H‐Bonded Assembly of Discrete [Co(en)~3~]^3+^, (Zr~2~F~12~)^4−^, and (SiF~6~)^2−^ Ions about?

Photofunctional materials are important because of their unique optical and electrical properties and are widely used in solar-energy conversion, semiconductor surface sensitization and modification, and nanoelectronics. [1][2][3][4][5] In recent decades, much effort has been directed toward the synthesis of pnictide-and chalcogenide-based inorganic semiconductor materials such as GaN, [6] SiC, [7] ZnO 2 , [8] and SnO 2 [9] because of their comparatively wide HOMO-LUMO gaps. There has been little investigation, however, of the photoelectronic properties of molecular solids. Recently, by using an optically pure or a racemic mixture of a chiral cobalt complex such as [Co(en) 3 Cl 3 ] or [Co-(dien) 2 Cl 3 ] as the template, we prepared a series of openframework metal phosphates and oxides with chiral structure characters. [10,11] In order to explore new metal fluorides formed with a chiral cobalt complex as the template, we prepared a new cobalt complex-containing zirconium-silicon compound, namely [Co(en) 3 ] 2 (Zr 2 F 12 )(SiF 6 )•4 H 2 O (1), which contains an H-bonded network of discrete [Co(en) 3 ] 3+ , [Zr 2 F 12 ] 4À , and [SiF 6 ] 2À ions. Unexpectedly, this new compound exhib

Who reads An Unexpected Photoelectronic Effect from [Co(en)~3~]~2~(Zr~2~F~12~)(SiF~6~)⋅4 H~2~O, a Compound Containing an H‐Bonded Assembly of Discrete [Co(en)~3~]^3+^, (Zr~2~F~12~)^4−^, and (SiF~6~)^2−^ Ions?

Author

Yu Du; Min Yang; Jihong Yu; Qinhe Pan; Ruren Xu

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley; Research Square (ISSN 0044-8249)

Published

2005

Language

EN

Field

Chemistry (Physical Sciences)